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- W2020491535 abstract "Abstract 8S-O-acetylepiclavolonine, a new Lycopodium alkaloid, was isolated from the Icelandic club moss Diphasiastrum alpinum and its structure and stereochemistry was determined using a combination of NMR spectroscopy and mass spectrometry. The previously described alkaloids 5R,8R-O-acetylfawcettiine, 5R,8S-O-acetyllofoline, lycodoline and anhydrolycodoline were found in D. alpinum for the first time together with previously reported lycopodine and clavolonine. The 1H NMR spectra of 8S-O-acetylepiclavolonine and 5R,8S-O-acetyllofoline, revealed a highly deshielded proton at ca. 12 ppm, which seems to be stabilized by an intramolecular hydrogen bond to the carbonyl oxygen of the 8S-O-acetyl group. The isolated alkaloids were tested toward acetylcholinesterase in vitro without showing significant inhibition." @default.
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- W2020491535 date "2013-08-01" @default.
- W2020491535 modified "2023-09-26" @default.
- W2020491535 title "Phytochemical analysis of alkaloids from the Icelandic club moss Diphasiastrum alpinum" @default.
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- W2020491535 doi "https://doi.org/10.1016/j.phytol.2013.04.004" @default.
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