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• W2020504721 abstract "While most of crystalline wide gap oxides are both stoichiometric and insulating, a handful of them including ZnO and ${mathrm{In}}_{2}{mathrm{O}}_{3}$ are naturally anion-deficient and electron conductors. Even fewer of the oxides are naturally cation-deficient and hole conductors, the arch-type of which is ${mathrm{Cu}}_{2}mathrm{O}$. Based on first principles calculation of equilibrium nonstoichiometry and defect stability, we explain why the ${mathrm{Cu}}^{(I)}({d}^{10})$ oxide-based materials are both $p$-type and naturally cation-deficient, and why cation vacancies lead to delocalized, conductive states, whereas in other oxides (e.g., ZnO and MgO), they lead to localized, nonconductive states." @default.
• W2020504721 created "2016-06-24" @default.
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• W2020504721 date "2007-07-16" @default.
• W2020504721 modified "2023-10-10" @default.
• W2020504721 title "Origins of the<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>p</mml:mi></mml:math>-type nature and cation deficiency in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mi mathvariant=normal>Cu</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:mi mathvariant=normal>O</mml:mi></mml:mrow></mml:math>and related materials" @default.
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• W2020504721 doi "https://doi.org/10.1103/physrevb.76.045209" @default.
• W2020504721 hasPublicationYear "2007" @default.
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