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- W2020532365 abstract "The Zn(II)/Zn(Tl+Ga) electrode reaction was studied at the dropping Tl+Ga alloy electrode with a bulk composition of 0.06 mol% thallium in acidified aqueous 1 M NaClO 4 solutions. By means of sampled dc voltammetry a strongly irreversible Zn(II)/Zn(Tl+Ga) wave was obtained, which occurred around E ° f =−0.989 V versus SSCE and was separated into a distinct anodic and cathodic branch. The kinetic parameters of the reaction were determined by analysis of the sampled dc wave and of the ac impedance. It was found that the overall Zn(II) reduction process proceeds via the two-step electron transfer mechanism, the first step of which is rate determining in the entire accessible potential region. At the Tl+Ga electrode the rate constant of the first step A 1 is three orders of magnitude smaller than that observed at pure gallium. This was discussed in terms of concomitant changes of the properties of the electrode surface and its interface with the electrolyte solution. These results are hard to reconcile with current theories on the kinetics of electrochemical electron transfer reactions." @default.
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- W2020532365 date "1999-08-01" @default.
- W2020532365 modified "2023-09-24" @default.
- W2020532365 title "Electrode kinetics and the nature of the metal electrode" @default.
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- W2020532365 doi "https://doi.org/10.1016/s0022-0728(99)00265-x" @default.
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