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- W2020538084 abstract "This paper reports the utility of simple metal alkoxides for the catalytic, stereoselective hetero-aldol−Tishchenko reaction (eq 1). Choice of metal alkoxide is crucial to achieving high efficiency and stereoselectivity. Whereas NaO-t-Bu is an effective catalyst, delivering one product in 68% yield and 99:1 stereoselection, Sm(O-i-Pr)3 is less effective and delivers the same product in 42% yield with 4:1 stereoselection." @default.
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- W2020538084 date "1999-10-06" @default.
- W2020538084 modified "2023-09-27" @default.
- W2020538084 title "Simple Metal Alkoxides as Effective Catalysts for the Hetero-Aldol−Tishchenko Reaction" @default.
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- W2020538084 doi "https://doi.org/10.1021/ol990246c" @default.
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