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• W2020538387 abstract "An upper-rim-substituted calix[4]arene tetracarboxylic acid forms hydrogen-bonded duplexes with lower-rim-substituted tetra(4-pyridyl)- and tetra(3-pyridyl)calix[4]arenes in chloroform. The formation of these adducts was studied by extraction experiments. The association constants determined via (1)H NMR dilution experiments in CDCl(3) are 7.6 x 10(3) and 1.3 x 10(3) M(-1) for the 4-pyridyl and the 3-pyridyl derivative, respectively. IR studies in the solid state and in solution indicate that the interaction is based on hydrogen bonding and that the degree of proton transfer is negligible. VPO measurements support the formation of 1:1 adducts." @default.
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• W2020538387 date "1996-01-01" @default.
• W2020538387 modified "2023-10-12" @default.
• W2020538387 title "Lower Rim−Upper Rim Hydrogen-Bonded Adducts of Calix[4]arenes" @default.
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• W2020538387 doi "https://doi.org/10.1021/jo9603082" @default.
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