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- W2020543358 abstract "Effect of Sn substitution on hydriding characteristics of FeTi has been studied for FeTi1−xSnx system (x = 0.02 and 0.05). Sn substitution in place of Ti results in an increase of plateau pressures, ΔH and ΔS values, and decrease in saturation hydrogen contents. For FeTi.95Sn.05 the ease of activation was found to be improved and a saturation hydride composition FeTi.95Sn.05H1.4 could be achieved in two activation cycles. The samples have been characterized by X-ray diffraction, 57Fe and 119Sn Mössbauer spectroscopy and differential scanning calorimetry. Sn substituted samples showed the existence of an additional Fe2Ti phase which appears to be responsible for the easy activation. The sealing characteristics of FeTi.95Sn.05H1.4 were found to be significantly improved as compared with FeTiH∼2. Unlike 57Fe Mössbauer spectra which clearly revealed the formation of β and γ hydride phases through change in isomeric shift and quadrupole splitting values, 119Sn spectra remained almost unaltered except the decrease in recoil free fraction on hydride formation." @default.
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- W2020543358 date "1988-03-01" @default.
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- W2020543358 title "Studies on hydrogen storage material FeTi: Effect of Sn substitution" @default.
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- W2020543358 doi "https://doi.org/10.1016/0025-5408(88)90006-2" @default.
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