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- W2020559307 abstract "Condensation of substituted cyclohexanones with cinnamaldehydes and morpholine in the presence of anhydrous cerium(III) chloride was carried out. The stereochemistry of the condensed products, variously substituted 2-morpholino-4-phenylbicyclo[3.3.1]nonan-9-ones, was deduced by using the 1H NMR COSY technique and 13C NMR data. In order to draw a general conclusion, the stereochemistry of the sterically comparable 2,4-diphenylbicyclo[3.3.1]nonan-9-one was also studied in detail, using 1H NMR COSY and 13C NMR data. A general conclusion regarding the boat-chair conformational preference for such sterically comparable cis-2,4-disubstituted bicyclo[3.3.1]nonan-9-ones has been deduced, with the substituted ring in the boat form and a diequatorial disposition of the two substituents." @default.
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- W2020559307 date "1987-11-01" @default.
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- W2020559307 title "Conformational studies of sterically comparable 2,4-disubstituted bicyclo[3.3.1]nonan-9-one systems" @default.
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- W2020559307 doi "https://doi.org/10.1002/mrc.1260251107" @default.
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