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- W2020561907 startingPage "2444" @default.
- W2020561907 abstract "Aryliminotriphenylphosphoranes reacted with methanesulfonyl, ethanesulfonyl and α-toluenesulfonyl chlorides in the presence of triethylamine to give 1 : 2 adducts [α-(N-alkanesulfonyl-N-arylsulfamoyl)alkylidenephosphoranes] and the decomposition products, instead of 1 : 1 adducts [α-(N-arylsulfamoyl)alkylidenephosphoranes). They were obtained under ice-cooling, the structure being of betaine type. In the case of methanesulfonyl chloride, isomeric 1 : 2 adduct [α-(N-arylsulfamoyl)methanesulfonylmethylenephosphorane] was also obtained. 2-Propanesulfonyl chloride gave N-triphenylphosphonio-N-arylsulfamate instead of expected adduct. In the absence of triethylamine, α-(N-arylsulfamoyl) alkyltriphenylphosphonium chlorides were obtained in good yields. Possible mechanisms of these reactions have been discussed." @default.
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- W2020561907 date "1974-10-01" @default.
- W2020561907 modified "2023-09-23" @default.
- W2020561907 title "Reactions of Aryliminotriphenylphosphoranes with Sulfenes" @default.
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- W2020561907 doi "https://doi.org/10.1246/bcsj.47.2444" @default.
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