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- W2020565132 abstract "The lateral crystal habit of polyethylene has been studied experimentally and theoretically. When the fraction of low-molecular-weight polyethylene (Mw = 2000 and MwMn = 1.1) is crystallized from n-hexacontane solution at high temperatures (T > 105°C), most chains are extended in the crystals and the lateral shape of single crystals becomes lenticular. The longer axis of the lenticular profile is parallel to the b axis of crystals and the tip has an acute angle; the {1 1 0} growth face disappears in this habit. The curved outline of the lenticular habit has been analysed with the kinetic theory of Seto and Frank on the basis of nucleation-controlled growth. A moving boundary condition has been applied to the growth of the crystal sector, as was done by Mansfield. It is shown that the lenticular habit is expected for strongly retarded crystallization on the {2 0 0} growth face." @default.
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- W2020565132 date "1991-01-01" @default.
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- W2020565132 title "Rounded lateral habits of polyethylene single crystals" @default.
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- W2020565132 doi "https://doi.org/10.1016/0032-3861(91)90498-8" @default.
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