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• W2020583014 endingPage "3965" @default.
• W2020583014 startingPage "3962" @default.
• W2020583014 abstract "The title compound adds to α,β-unsaturated carbonyls to give the products of 1,4-addition after hydrolysis of the intermediate boron enolates, in 68−86% isolated yield (four examples). In addition, we discovered that diazomethane reacts with bis(pinacolato)diborane to insert methylene to give (pinacolato)2BCH2B in 83% yield. An alternative synthesis involved coupling of (pinacolato)BCH2I with various metals." @default.
• W2020583014 created "2016-06-24" @default.
• W2020583014 creator A5033602178 @default.
• W2020583014 creator A5058991707 @default.
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• W2020583014 date "2001-08-03" @default.
• W2020583014 modified "2023-10-07" @default.
• W2020583014 title "Addition Reactions of Bis(pinacolato)diborane(4) to Carbonyl Enones and Synthesis of (pinacolato)₂BCH₂B and (pinacolato)₂BCH₂CH₂B by Insertion and Coupling" @default.
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• W2020583014 doi "https://doi.org/10.1021/om010282r" @default.
• W2020583014 hasPublicationYear "2001" @default.
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