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• W2020591193 abstract "Nanostructured titanium oxide films synthesized by supersonic cluster beam deposition were analyzed by high-resolution transmission electron microscopy. Nanoparticles were produced in a pulsed microplasma cluster source in the presence of He or helium-oxygen mixture as carrier gas. While films grown using He consist only of rutile and anatase TiO2 nanocrystals formed upon exposure to air, films grown with a He∕O mixture also contain isolated TiOx cages that closely resemble carbon fullerenes. The diameter of the cages ranges from about 0.9to2.7nm. A fraction of the cages have irregular shapes, possibly induced by oxygen vacancies. The TiOx fullerenoids grow in the gas phase, in a narrow temperature/pressure range within the cluster source, and are preserved through low-energy deposition." @default.
• W2020591193 created "2016-06-24" @default.
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• W2020591193 date "2005-11-08" @default.
• W2020591193 modified "2023-10-03" @default.
• W2020591193 title "Titanium fullerenoid oxides" @default.
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• W2020591193 doi "https://doi.org/10.1063/1.2128489" @default.
• W2020591193 hasPublicationYear "2005" @default.
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