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• W2020642270 abstract "A kinetic study on the ring-opening polymerization (ROP) of octamethylcyclotetrasiloxane (D4) in miniemulsion is presented in this work. The polymerization is initiated by dodecylbenzenesulfonic acid (DBSA) which also serves as the surfactant (inisurf). The influence of the size of monomer droplet and the concentration of DBSA on the polymerization rate were studied. Since the main place for the ROP of D4 was confirmed to be at the oil/water interface, a three-layer interface model was proposed to analyze the distribution of molecules at the interface and the effects of DBSA. A kinetic equation is then developed based on this model. In the equation, the polymerization rate (Rp) is related to the initial monomer concentration ([D4]0), the droplet radius (r), the coverage of DBSA on monomer droplets surface (x). The polymerization rate can be predicted from the kinetic equation feeding all parameters with their experimental values. Finally, the equation gave a good accordance between the predicted polymerization rate data and the experimental results under different polymerization conditions." @default.
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• W2020642270 creator A5024990016 @default.
• W2020642270 creator A5078983476 @default.
• W2020642270 creator A5082020327 @default.
• W2020642270 date "2010-08-01" @default.
• W2020642270 modified "2023-09-27" @default.
• W2020642270 title "Kinetic study on the ring-opening polymerization of octamethylcyclotetrasiloxane (D4) in miniemulsion" @default.
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• W2020642270 doi "https://doi.org/10.1016/j.polymer.2010.06.038" @default.
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