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• W2020659436 startingPage "839" @default.
• W2020659436 abstract "The dielectric relaxation behaviour of several amorphous low molecular weight carbohydrates and their 10% w/w water mixtures has been studied in the supercooled liquid and glassy regions in the frequency range 100 Hz to 100 kHz. The dry carbohydrates show a primary α-relaxation (activation energy 250–405 kJ mol−1) at temperatures above the calorimetric glass transition temperature, Tg, and, in most cases, a secondary β-relaxation (activation energy 42–55 kJ mol−1) at sub-Tg temperatures. Whilst d-mannose showed a β-relaxation similar in strength to d-glucose, its deoxy sugar, l-rhamnose showed a relatively weak β-relaxation. This indicates that the hydroxymethyl group influences relaxation in carbohydrate glasses. Addition of water shifted the α-relaxations to lower temperatures and increased the strength of the β-relaxations. In glucitol this resulted in a merging of the α- and β-relaxations. The β-relaxation increased in strength and decreased in temperature for the series of water mixtures: d-glucose, maltose, and maltotriose." @default.
• W2020659436 created "2016-06-24" @default.
• W2020659436 creator A5010605024 @default.
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• W2020659436 date "2000-12-01" @default.
• W2020659436 modified "2023-10-16" @default.
• W2020659436 title "Effect of molecular structure and water content on the dielectric relaxation behaviour of amorphous low molecular weight carbohydrates above and below their glass transition" @default.
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• W2020659436 doi "https://doi.org/10.1016/s0008-6215(00)00227-5" @default.
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