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• W2020697075 endingPage "94" @default.
• W2020697075 startingPage "88" @default.
• W2020697075 abstract "The novel ligand 1-(2,4,6-trimethylbenzyl)-2-(2′-pyridyl)benzimidazole and its heteroleptic ruthenium (II) complex were synthesized. The complex was characterized using spectroscopic methods and cyclic voltammetry. Charge-separation was investigated within nanoporous titanium dioxide employing surface photovoltage spectroscopy. The performance of the ruthenium complex as a charge transfer photosensitizer in nanocrystalline, titanium dioxide-based, dye sensitized solar cells was studied under standard AM 1.5 sunlight using an electrolyte consisting of 0.6 M 1-butyl-3-methyl-imidazolium iodide, 0.1 M lithium iodide, 0.05 M iodine and 0.5 M 4-tert-butyl pyridine in 3-methoxy propyonitrile. The novel complex had a photocurrent density of 9.47 mA cm−2, 600 mV open circuit potential and 0.60 fill factor yielding an efficiency of 3.4%. The photovoltaic performance of the colorant was compared with that of cis-bis(isothiocyanato)(2,2'-bipyridyl-4,4'-dicarboxylato) (2,2’-bipyridyl-4,4’-di-nonyl) ruthenium(II); both compounds exhibited similar efficiency, while the fill factor value was higher for the novel dye." @default.
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• W2020697075 date "2010-01-01" @default.
• W2020697075 modified "2023-10-18" @default.
• W2020697075 title "The synthesis and characterization of 2-(2′-pyridyl)benzimidazole heteroleptic ruthenium complex: Efficient sensitizer for molecular photovoltaics" @default.
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• W2020697075 doi "https://doi.org/10.1016/j.dyepig.2009.06.016" @default.
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