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- W2020698498 abstract "The plateau yields of hydrogen from the Febetron radiolysis of mixtures of water vapor with up to 8 mol% of HCl or HBr are G(H 2 ) = 7.9 ± 0.2 and G(H 2 ) = 4.6 ± 0.2 with 1 mol% SF 6 . These yields are consistent with G(H) = 7.45 in pure water vapor and G(H) = 4.15 in water vapor with SF 6 . In the Febetron radiolysis of pure water vapor at 2 × 10 27 eV g −1 s −1 and densities of ~1 mg ml −1 G(H 2 ) = 1.65 + 0.05 from 164 to 190 °C. This yield is reduced to G(H 2 ) = 0.90 ± 0.05 on the addition of 1 mol% SF 6 . Using a second order equivalent rate constant for the disappearance of the OH radicals in water vapor at 1 mg ml −1 of 2 × 10 10 M −1 s −1 these yields are consistent with ate constant values for the reactions H + OH (+H 2 O) → H 2 O, OH + OH (+H 2 O) → H 2 O 2 , and H + H (+H 2 O) → H 2 , of 1.7 ± 0.1 × 10 10 M − 1 s −1 , 1.5 ± 0.5 × 10 9 M −1 s −1 , and 3 ± 1 × 10 8 M −1 s −1 , respectively." @default.
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- W2020698498 title "The Radiolysis of Water Vapor at Very High Dose Rates. I. Hydrogen Yields from H<sub>2</sub>O, H<sub>2</sub>O–HCl, and H<sub>2</sub>O–HBr Mixtures" @default.
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