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• W2020730852 abstract "Reactions of H atoms with COS, CS2, and H2S were studied behind reflected shock waves at temperatures between 1170 K and 1830 K and pressures around 1.0 bar by applying atomic resonance absorption spectroscopy (ARAS) for time-resolved measurements of H atoms at Lα. The thermal decomposition of a few ppm ethyl iodide (C2H5I) was used as a H-atom source. In the presence of a large excess of the molecular reactant COS, CS2, or H2S, a consumption of H was observed which follows a pseudo first-order rate law. Rate coefficients for the reactions:were determined to be:k1 = 2.4 × 1014exp(–3415 K/T) cm3mol−1s−1k2 = 1.4 × 1015exp(–9250 K/T) cm3mol−1s−1k3 = 2.5 × 1014exp(–2890 K/T) cm3mol−1s−1" @default.
• W2020730852 created "2016-06-24" @default.
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• W2020730852 date "1996-01-01" @default.
• W2020730852 modified "2023-09-24" @default.
• W2020730852 title "A Shock Tube Study of the Reactions of H Atoms with COS, CS2, and H2S" @default.
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• W2020730852 doi "https://doi.org/10.1002/ijch.199600039" @default.
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