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• W2020762013 endingPage "793" @default.
• W2020762013 startingPage "786" @default.
• W2020762013 abstract "LiFePO4/C and LiFe1−xNixPO4/C (x = 0, 0.02, 0.04, and 0.06) composites were prepared using solid-state reaction. The as-prepared composites were characterized by using X-ray diffraction, charge–discharge cycling, cyclic voltammograms, Raman spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and other techniques. The experimental results show that all as-prepared composites have a single phase of orthorhombic olivine-type structure with the Pnmb space group. The as-prepared LiFe1−xNixPO4/C composites exhibit high capacities and good cycling performance; e.g., the LiFe0.98Ni0.02PO4/C composite delivers 142 and 138 mAh g−1 at the 0.1 C rate for the first and fifth cycles, respectively. Such composites also show good rate capabilities; e.g., when discharged at the 2 C rate the LiFe0.98Ni0.02PO4/C composite delivers an initial capacity of 121 mAh g−1, 85% of the discharge capacity at the 0.1 C rate. The reason why the LiFe1−xNixPO4/C composites have better electrochemical performance compared to the LiFePO4/C composites is because nickel doping enhances the PO bond, stabilizes the structure, and thus the charge-transfer resistance and cathode particle resistance of the composites are decreased." @default.
• W2020762013 created "2016-06-24" @default.
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• W2020762013 date "2009-12-01" @default.
• W2020762013 modified "2023-10-11" @default.
• W2020762013 title "Synthesis of LiFe1−xNixPO4/C composites and their electrochemical performance" @default.
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• W2020762013 doi "https://doi.org/10.1016/j.jpowsour.2009.05.041" @default.
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