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• W2020776639 abstract "Abstract The solid solubility of the SrAl 2 O 4 –CaAl 2 O 4 system was investigated. Both XRD patterns and cathodoluminescence from Eu 2+ in the host lattices were utilized to investigate the solid solubility of SrAl 2 O 4 in CaAl 2 O 4 . A single phase exists in the range x = 1 to x = 0.5 in Sr 1−x Ca x Al 2 O 4 composition (i.e., the [CaAl 2 O 4 ] phase exists as a single phase from CaAl 2 O 4 to Sr 0.5 Ca 0.5 Al 2 O 4 ). The luminescence band maximum of Eu 2+ in [CaAl 2 O 4 ] phase shifts from 433 nm (CaAl 2 O 4 :Eu 2+ ) to 404 nm (Sr 0.9 Ca 0.1 Al 2 O 4 :Eu 2+ ). The blue-shift behavior of Eu 2+ emission can be explained in terms of Eu 2+ experiencing the weakening of crystal field strength with the decreasing x value of Sr 1−x Ca x Al 2 O 4 :Eu 2+ (0.01%). This phenomenon confirms that Blasse’s prediction regarding the Eu 2+ crystal field-dependent 4 f 6 5 d 1 energy level is applicable in oxide hosts." @default.
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• W2020776639 date "1999-09-01" @default.
• W2020776639 modified "2023-09-24" @default.
• W2020776639 title "Determination of the solid solubility of SrAl2o4 in CaAl2o4 through crystal field-dependent Eu2+ signatures" @default.
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• W2020776639 doi "https://doi.org/10.1016/s0025-5408(99)00201-9" @default.
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