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- W2020785803 abstract "Abstract The kinetics of the reaction of O 3 with the aromatic vicinal diols 1,2‐benzenediol, 3‐methyl‐1,2‐benzenediol, and 4‐methyl‐1,2‐benzenediol have been investigated using a relative rate technique. The rate coefficients were determined in a 1080‐L smog chamber at 298 K and 1 atm total pressure of synthetic air using propene and 1,3‐butadiene as reference compounds. The following O 3 reaction rate coefficients (in units of cm 3 molecule −1 s −1 ) have been obtained: k (1,2‐benzenediol) = (9.60 ± 1.12) × 10 −18 , k (3‐methyl‐1,2‐benzenediol) = (2.81 ± 0.23) × 10 −17 , k (4‐methyl‐1,2‐benzenediol) = (2.63 ± 0.34) × 10 −17 . Absolute measurements of the O 3 rate coefficient have also been carried out by measuring the decay of the dihydroxy compound in an excess of O 3 . The results from these experiments are in good agreement with the relative determinations. Atmospheric implications are discussed. © 2003 Wiley Periodicals, Inc. Int J Chem Kinet 35: 223–230, 2003" @default.
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- W2020785803 date "2003-01-01" @default.
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- W2020785803 title "Kinetics of the reaction of O3 with selected benzenediols" @default.
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- W2020785803 doi "https://doi.org/10.1002/kin.10121" @default.
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