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• W2020841060 abstract "Water-oil partitioning rates are reported for a chemically diverse set of solutes with 4 solvents: CHC13, 2,2,4-trimethylpentane, octanol and propylene glycol dipelargonate acting as oil phase, in a rotating diffusion cell. A predictive model for partitioning rates in terms of fundamental physicochemical properties of the solutes and solvents has been developed. Anomalous aqueous diffusivity effects found previously in simple stirred two-phase cells are shown to be absent in the hydrodynamically well-defined rotating diffusion cell system. A small but necessary dependence of partitioning on solute molecular volume is demonstrated. No evidence is found for the existence of a measurable water-oil interfacial resistance to solute transfer." @default.
• W2020841060 created "2016-06-24" @default.
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• W2020841060 date "1989-03-01" @default.
• W2020841060 modified "2023-09-24" @default.
• W2020841060 title "A general description of water-oil partitioning rates using the rotating diffusion cell" @default.
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• W2020841060 doi "https://doi.org/10.1016/0378-5173(89)90136-1" @default.
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