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- W2020850532 abstract "Experimental results are reported for gas-phase reactions of Fe+ coordinated to the π-donating ligands C2H4, c-C5H5, C6H6 and C60 with N2O and CO. Reaction rate coefficients and product distributions were measured with the selected-ion flow tube (SIFT) technique operating at 294 ± 3 K and a helium buffer gas pressure of 0.35 ± 0.01 Torr. The measurements provide intrinsic efficiencies for the primary and higher-order ligation of these XFe+ cations with CO and N2O and their corresponding coordination numbers. The coordination numbers are consistent with known ground state electronic structures. Many of the ligated ions were synthesized by ion/molecule ligation reactions in the gas phase for the first time, including XFe(CO)n+ and XFe(N2O)+ with X C2H4, c-C5H5 and C6H6, (C60)Fe(N2O)+, (C60)FeO+ and (C60)FeO(N2O)+. Also, the measurements provided an experimental assessment of the mode of bonding in (C60)Fe+." @default.
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- W2020850532 title "Reactions of Fe+ coordinated to the π-donating ligands C2H4, c-C5H5, C6H6 and C60 with N2O and CO: probing the bonding in (C60)Fe+" @default.
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- W2020850532 doi "https://doi.org/10.1016/0168-1176(95)04287-u" @default.
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