FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2020860121> ?p ?o ?g. }

• W2020860121 endingPage "8722" @default.
• W2020860121 startingPage "8715" @default.
• W2020860121 abstract "The bis-bidentate bridging function of gbha2- with N,O-/N,O- coordination was observed for the first time in the complex (μ-gbha)[RuIII(acac)2]2 (1). Density functional theory calculations of 1 yield a triplet ground state with a large (ΔE > 6000 cm-1) singlet−triplet gap. Intermolecular antiferromagnetic coupling was observed (J ≈ −5.3 cm-1) for the solid. Complex 1 undergoes two one-electron reduction and two one-electron oxidation steps; the five redox forms {(μ-gbha)[Ru(acac)2]2}n (n = −2, −1, 0, +1, +2) were characterized by UV−vis−NIR spectroelectrochemistry (NIR = near infrared). The paramagnetic intermediates were also investigated by electron paramagnetic resonance (EPR) spectroscopy. The monoanion with a comproportionation constant Kc of 2.7 × 108 does not exhibit an NIR band for a RuIII/RuII mixed-valent situation; it is best described as a 1,4-diazabutadiene radical anion containing ligand gbha•3-, which binds two ruthenium(III) centers. A RuIII-type EPR spectrum with g1 = 2.27, g2 = 2.21, and g3 = 1.73 is observed as a result of antiferromagnetic coupling between one RuIII and the ligand radical. The EPR-active monocation (Kc = 1.7 × 106) exhibits a broad (Δν1/2 = 2600 cm-1) intervalence charge-transfer band at 1800 nm, indicating a valence-averaged (Ru3.5)2 formulation (class III) with a tendency toward class II (borderline situation)." @default.
• W2020860121 created "2016-06-24" @default.
• W2020860121 creator A5007237862 @default.
• W2020860121 creator A5018152460 @default.
• W2020860121 creator A5018528585 @default.
• W2020860121 creator A5019732428 @default.
• W2020860121 creator A5020043051 @default.
• W2020860121 creator A5020335865 @default.
• W2020860121 creator A5029762694 @default.
• W2020860121 creator A5044932511 @default.
• W2020860121 creator A5062826786 @default.
• W2020860121 creator A5084792068 @default.
• W2020860121 date "2005-10-19" @default.
• W2020860121 modified "2023-10-16" @default.
• W2020860121 title "A New Coordination Mode of the Photometric Reagent Glyoxalbis(2-hydroxyanil) (H₂gbha): Bis-Bidentate Bridging by gbha²^- in the Redox Series {(μ-gbha)[Ru(acac)₂]₂}<i>ⁿ</i> (<i>n</i> = −2, −1, 0, +1, +2), Including a Radical-Bridged Diruthenium(III) and a Ru^III/Ru^IV Intermediate" @default.
• W2020860121 cites W1504277857 @default.
• W2020860121 cites W1691067281 @default.
• W2020860121 cites W1942355807 @default.
• W2020860121 cites W1969351707 @default.
• W2020860121 cites W1980214671 @default.
• W2020860121 cites W1985316787 @default.
• W2020860121 cites W1987141277 @default.
• W2020860121 cites W1987771226 @default.
• W2020860121 cites W1990376738 @default.
• W2020860121 cites W1992435922 @default.
• W2020860121 cites W1995064448 @default.
• W2020860121 cites W1996632835 @default.
• W2020860121 cites W1999536270 @default.
• W2020860121 cites W1999832496 @default.
• W2020860121 cites W2001465174 @default.
• W2020860121 cites W2004436374 @default.
• W2020860121 cites W2004552089 @default.
• W2020860121 cites W2015723183 @default.
• W2020860121 cites W2019214481 @default.
• W2020860121 cites W2021616354 @default.
• W2020860121 cites W2022129332 @default.
• W2020860121 cites W2023271753 @default.
• W2020860121 cites W2027845130 @default.
• W2020860121 cites W2028432591 @default.
• W2020860121 cites W2030175511 @default.
• W2020860121 cites W2030271846 @default.
• W2020860121 cites W2033365705 @default.
• W2020860121 cites W2039642201 @default.
• W2020860121 cites W2040766488 @default.
• W2020860121 cites W2045552677 @default.
• W2020860121 cites W2048046882 @default.
• W2020860121 cites W2050082735 @default.
• W2020860121 cites W2050746047 @default.
• W2020860121 cites W2062362631 @default.
• W2020860121 cites W2063522347 @default.
• W2020860121 cites W2067255882 @default.
• W2020860121 cites W2067775265 @default.
• W2020860121 cites W2069198899 @default.
• W2020860121 cites W2076213347 @default.
• W2020860121 cites W2077985496 @default.
• W2020860121 cites W2081816792 @default.
• W2020860121 cites W2086957099 @default.
• W2020860121 cites W2090065184 @default.
• W2020860121 cites W2105510993 @default.
• W2020860121 cites W2115495367 @default.
• W2020860121 cites W213791877 @default.
• W2020860121 cites W2150613327 @default.
• W2020860121 cites W2163550414 @default.
• W2020860121 cites W2164889025 @default.
• W2020860121 cites W2169489156 @default.
• W2020860121 cites W2169775732 @default.
• W2020860121 cites W2497007159 @default.
• W2020860121 cites W2501886121 @default.
• W2020860121 cites W2951932022 @default.
• W2020860121 cites W2952695194 @default.
• W2020860121 doi "https://doi.org/10.1021/ic050950r" @default.
• W2020860121 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16296825" @default.
• W2020860121 hasPublicationYear "2005" @default.
• W2020860121 type Work @default.
• W2020860121 sameAs 2020860121 @default.
• W2020860121 citedByCount "49" @default.
• W2020860121 countsByYear W20208601212012 @default.
• W2020860121 countsByYear W20208601212013 @default.
• W2020860121 countsByYear W20208601212014 @default.
• W2020860121 countsByYear W20208601212015 @default.
• W2020860121 countsByYear W20208601212016 @default.
• W2020860121 countsByYear W20208601212017 @default.
• W2020860121 countsByYear W20208601212018 @default.
• W2020860121 countsByYear W20208601212020 @default.
• W2020860121 countsByYear W20208601212022 @default.
• W2020860121 countsByYear W20208601212023 @default.
• W2020860121 crossrefType "journal-article" @default.
• W2020860121 hasAuthorship W2020860121A5007237862 @default.
• W2020860121 hasAuthorship W2020860121A5018152460 @default.
• W2020860121 hasAuthorship W2020860121A5018528585 @default.
• W2020860121 hasAuthorship W2020860121A5019732428 @default.
• W2020860121 hasAuthorship W2020860121A5020043051 @default.
• W2020860121 hasAuthorship W2020860121A5020335865 @default.
• W2020860121 hasAuthorship W2020860121A5029762694 @default.
• W2020860121 hasAuthorship W2020860121A5044932511 @default.
• W2020860121 hasAuthorship W2020860121A5062826786 @default.
• W2020860121 hasAuthorship W2020860121A5084792068 @default.
• W2020860121 hasConcept C115624301 @default.

• next