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• W2020884049 abstract "Several of the ways in which diffusion of an electroactive species may affect the small-signalresponse of an electrochemical system are examined, with particular attention to cases in which the electrode reaction produces or consumes a neutral species whose concentration at the electrode surface is determined by diffusion through the electrode. The conventional (time domain) rate and diffusion equations may be expressed in the frequency domain through the use of complex, frequency-dependent rate constants, whose form reflects the sequence of events in the overall reaction, including possible adsorption steps, and leads directly to equivalent-circuit representations of the pertinent parts of the system response. The complex rate constant formalism also allows the immediate generalization of existing exact treatments of unsupported systems to include such diffusion effects." @default.
• W2020884049 created "2016-06-24" @default.
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• W2020884049 date "1979-08-01" @default.
• W2020884049 modified "2023-09-23" @default.
• W2020884049 title "Diffusion of neutral and charged species under small-signal a.c. conditions" @default.
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• W2020884049 doi "https://doi.org/10.1016/s0022-0728(79)80042-x" @default.
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