FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2020946070> ?p ?o ?g. }

• W2020946070 endingPage "368" @default.
• W2020946070 startingPage "331" @default.
• W2020946070 abstract "A modified form of Tung's integral equation allows the variance M 2p of the observed polymer chromatogram to be expanded as the sum of the main contribution due to molecular weight distribution plus the band spreading contribution μ2 (the variance of a single component chromatogram being eluted, at the same average elution volume) and a series of correction terms negligible for narrow molecular weight distribution. A model of the chromatographic separation taking into account hydrodynamical and diffusional spreading effects in each of the different columns in the apparatus leads to a Van Deemter's relationship relating μ2 to solvent flowrate. The coupling of the two above quoted relationships was used to exploit experimental measurements of M 2p for anionically polymerized polystyrene samples vs. solvent flowrate in a set of 3 μ-styragel R columns having nominal pores sizes 103, 104 and 105 Å. These measurements, as well as previous work (where methods of treatment of data are discussed) were used to bring information on polymer intraparticle diffusion. Simulation based studies were undertaken in order to arrive at a simplified representation of chromatographic peak shape. Peak skewing in ordinary conditions was shown to be small. This explains that no appreciable error is made when using Hamielec and Ray's original formulae for correcting apparent (band spreading distorted) average molecular weights, although these formulae assume single component peaks to be gaussian, which is not correct." @default.
• W2020946070 created "2016-06-24" @default.
• W2020946070 creator A5024830987 @default.
• W2020946070 creator A5036562824 @default.
• W2020946070 creator A5054725569 @default.
• W2020946070 creator A5079391187 @default.
• W2020946070 date "1987-01-01" @default.
• W2020946070 modified "2023-10-14" @default.
• W2020946070 title "BAND SPREADING MODELING AND CORRECTION IN SIZE EXCLUSION CHROMATOGRAPHY PART I LINEAR CHROMATOGRAPHY THEORY AND THE PREDICTION OF THE SHAPE OF SINGLE COMPONENT CHROMATOGRAMS" @default.
• W2020946070 cites W1501195697 @default.
• W2020946070 cites W1965103059 @default.
• W2020946070 cites W2009285953 @default.
• W2020946070 cites W2020760531 @default.
• W2020946070 cites W2034267325 @default.
• W2020946070 cites W2056814676 @default.
• W2020946070 cites W2059499962 @default.
• W2020946070 cites W2061171222 @default.
• W2020946070 cites W2063011580 @default.
• W2020946070 cites W2072460229 @default.
• W2020946070 cites W2089898535 @default.
• W2020946070 cites W2100391092 @default.
• W2020946070 cites W2101975453 @default.
• W2020946070 cites W2151831050 @default.
• W2020946070 cites W2505348564 @default.
• W2020946070 cites W2903052324 @default.
• W2020946070 cites W4238580586 @default.
• W2020946070 cites W2057662908 @default.
• W2020946070 doi "https://doi.org/10.1080/00986448708911811" @default.
• W2020946070 hasPublicationYear "1987" @default.
• W2020946070 type Work @default.
• W2020946070 sameAs 2020946070 @default.
• W2020946070 citedByCount "2" @default.
• W2020946070 crossrefType "journal-article" @default.
• W2020946070 hasAuthorship W2020946070A5024830987 @default.
• W2020946070 hasAuthorship W2020946070A5036562824 @default.
• W2020946070 hasAuthorship W2020946070A5054725569 @default.
• W2020946070 hasAuthorship W2020946070A5079391187 @default.
• W2020946070 hasConcept C113196181 @default.
• W2020946070 hasConcept C121332964 @default.
• W2020946070 hasConcept C143724316 @default.
• W2020946070 hasConcept C147597530 @default.
• W2020946070 hasConcept C151730666 @default.
• W2020946070 hasConcept C163716315 @default.
• W2020946070 hasConcept C168727773 @default.
• W2020946070 hasConcept C172120300 @default.
• W2020946070 hasConcept C17744445 @default.
• W2020946070 hasConcept C178790620 @default.
• W2020946070 hasConcept C179998833 @default.
• W2020946070 hasConcept C181199279 @default.
• W2020946070 hasConcept C185592680 @default.
• W2020946070 hasConcept C18762648 @default.
• W2020946070 hasConcept C193363816 @default.
• W2020946070 hasConcept C199539241 @default.
• W2020946070 hasConcept C2776359362 @default.
• W2020946070 hasConcept C2777922577 @default.
• W2020946070 hasConcept C43617362 @default.
• W2020946070 hasConcept C521977710 @default.
• W2020946070 hasConcept C55493867 @default.
• W2020946070 hasConcept C69357855 @default.
• W2020946070 hasConcept C73826308 @default.
• W2020946070 hasConcept C86803240 @default.
• W2020946070 hasConcept C94625758 @default.
• W2020946070 hasConcept C97355855 @default.
• W2020946070 hasConceptScore W2020946070C113196181 @default.
• W2020946070 hasConceptScore W2020946070C121332964 @default.
• W2020946070 hasConceptScore W2020946070C143724316 @default.
• W2020946070 hasConceptScore W2020946070C147597530 @default.
• W2020946070 hasConceptScore W2020946070C151730666 @default.
• W2020946070 hasConceptScore W2020946070C163716315 @default.
• W2020946070 hasConceptScore W2020946070C168727773 @default.
• W2020946070 hasConceptScore W2020946070C172120300 @default.
• W2020946070 hasConceptScore W2020946070C17744445 @default.
• W2020946070 hasConceptScore W2020946070C178790620 @default.
• W2020946070 hasConceptScore W2020946070C179998833 @default.
• W2020946070 hasConceptScore W2020946070C181199279 @default.
• W2020946070 hasConceptScore W2020946070C185592680 @default.
• W2020946070 hasConceptScore W2020946070C18762648 @default.
• W2020946070 hasConceptScore W2020946070C193363816 @default.
• W2020946070 hasConceptScore W2020946070C199539241 @default.
• W2020946070 hasConceptScore W2020946070C2776359362 @default.
• W2020946070 hasConceptScore W2020946070C2777922577 @default.
• W2020946070 hasConceptScore W2020946070C43617362 @default.
• W2020946070 hasConceptScore W2020946070C521977710 @default.
• W2020946070 hasConceptScore W2020946070C55493867 @default.
• W2020946070 hasConceptScore W2020946070C69357855 @default.
• W2020946070 hasConceptScore W2020946070C73826308 @default.
• W2020946070 hasConceptScore W2020946070C86803240 @default.
• W2020946070 hasConceptScore W2020946070C94625758 @default.
• W2020946070 hasConceptScore W2020946070C97355855 @default.
• W2020946070 hasIssue "4-6" @default.
• W2020946070 hasLocation W20209460701 @default.
• W2020946070 hasOpenAccess W2020946070 @default.
• W2020946070 hasPrimaryLocation W20209460701 @default.
• W2020946070 hasRelatedWork W1973289178 @default.
• W2020946070 hasRelatedWork W1973362631 @default.
• W2020946070 hasRelatedWork W2005165146 @default.
• W2020946070 hasRelatedWork W2046089246 @default.
• W2020946070 hasRelatedWork W2058904997 @default.

• next