Matches in SemOpenAlex for { <https://semopenalex.org/work/W2020948696> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2020948696 endingPage "388" @default.
- W2020948696 startingPage "383" @default.
- W2020948696 abstract "The microwave spectrum of methyl monofluorosilane has been investigated in the region 18 to 38 kmc. Several transitions of the isotopic species CH3SiH2F and CH3SiD2F are split into doublets because of coupling of internal and over-all rotation. These splittings give a barrier to internal rotation of 1559±30 cal/mole. The form of the potential barrier was assumed to be V=12V3(1−cos3α). A few transitions belonging to the first excited torsional state were observed and assigned. The splittings in the excited state are consistent with the barrier as determined from ground state observations. Rotational constants of CH3SiH2F, CH3SiD2F, C13H3SiH2F, CD3SiH2F, and CH3SiDHF have been determined and were used to calculate the structure of the molecule. The structural parameters are: SiC1.848 ACSiF109∘ 13′SiF1.600HCH107∘ 52′SiH1.473CSiH109∘ 28′ (assumed)CH1.090HSiH109∘ 28′ (assumed). A study of CH2DSiH2F proves conclusively that methyl monofluorosilane in its equilibrium configuration has the methyl group staggered with respect to the SiH2F group. The dipole moment was found to be 1.71D." @default.
- W2020948696 created "2016-06-24" @default.
- W2020948696 creator A5082281781 @default.
- W2020948696 date "1958-08-01" @default.
- W2020948696 modified "2023-09-23" @default.
- W2020948696 title "Microwave Spectrum, Internal Barrier, Structure, Equilibrium Configuration, and Dipole Moment of Methyl Monofluorosilane" @default.
- W2020948696 cites W1578019195 @default.
- W2020948696 cites W1973058122 @default.
- W2020948696 cites W2050818385 @default.
- W2020948696 cites W2062377732 @default.
- W2020948696 cites W2063150399 @default.
- W2020948696 cites W2073885507 @default.
- W2020948696 cites W2143247420 @default.
- W2020948696 doi "https://doi.org/10.1063/1.1744489" @default.
- W2020948696 hasPublicationYear "1958" @default.
- W2020948696 type Work @default.
- W2020948696 sameAs 2020948696 @default.
- W2020948696 citedByCount "50" @default.
- W2020948696 countsByYear W20209486962012 @default.
- W2020948696 countsByYear W20209486962015 @default.
- W2020948696 countsByYear W20209486962019 @default.
- W2020948696 crossrefType "journal-article" @default.
- W2020948696 hasAuthorship W2020948696A5082281781 @default.
- W2020948696 hasConcept C121332964 @default.
- W2020948696 hasConcept C127413603 @default.
- W2020948696 hasConcept C147597530 @default.
- W2020948696 hasConcept C173523689 @default.
- W2020948696 hasConcept C178790620 @default.
- W2020948696 hasConcept C179254644 @default.
- W2020948696 hasConcept C181500209 @default.
- W2020948696 hasConcept C184779094 @default.
- W2020948696 hasConcept C185592680 @default.
- W2020948696 hasConcept C2778565081 @default.
- W2020948696 hasConcept C2781311116 @default.
- W2020948696 hasConcept C2994254730 @default.
- W2020948696 hasConcept C32909587 @default.
- W2020948696 hasConcept C41999313 @default.
- W2020948696 hasConcept C62520636 @default.
- W2020948696 hasConcept C69523127 @default.
- W2020948696 hasConcept C78519656 @default.
- W2020948696 hasConceptScore W2020948696C121332964 @default.
- W2020948696 hasConceptScore W2020948696C127413603 @default.
- W2020948696 hasConceptScore W2020948696C147597530 @default.
- W2020948696 hasConceptScore W2020948696C173523689 @default.
- W2020948696 hasConceptScore W2020948696C178790620 @default.
- W2020948696 hasConceptScore W2020948696C179254644 @default.
- W2020948696 hasConceptScore W2020948696C181500209 @default.
- W2020948696 hasConceptScore W2020948696C184779094 @default.
- W2020948696 hasConceptScore W2020948696C185592680 @default.
- W2020948696 hasConceptScore W2020948696C2778565081 @default.
- W2020948696 hasConceptScore W2020948696C2781311116 @default.
- W2020948696 hasConceptScore W2020948696C2994254730 @default.
- W2020948696 hasConceptScore W2020948696C32909587 @default.
- W2020948696 hasConceptScore W2020948696C41999313 @default.
- W2020948696 hasConceptScore W2020948696C62520636 @default.
- W2020948696 hasConceptScore W2020948696C69523127 @default.
- W2020948696 hasConceptScore W2020948696C78519656 @default.
- W2020948696 hasIssue "2" @default.
- W2020948696 hasLocation W20209486961 @default.
- W2020948696 hasOpenAccess W2020948696 @default.
- W2020948696 hasPrimaryLocation W20209486961 @default.
- W2020948696 hasRelatedWork W1017473139 @default.
- W2020948696 hasRelatedWork W1999339278 @default.
- W2020948696 hasRelatedWork W2021613149 @default.
- W2020948696 hasRelatedWork W2037964353 @default.
- W2020948696 hasRelatedWork W2075580158 @default.
- W2020948696 hasRelatedWork W2093808045 @default.
- W2020948696 hasRelatedWork W2137503715 @default.
- W2020948696 hasRelatedWork W2241422244 @default.
- W2020948696 hasRelatedWork W2266149758 @default.
- W2020948696 hasRelatedWork W2941448768 @default.
- W2020948696 hasVolume "29" @default.
- W2020948696 isParatext "false" @default.
- W2020948696 isRetracted "false" @default.
- W2020948696 magId "2020948696" @default.
- W2020948696 workType "article" @default.