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- W2020955081 abstract "Abstract The effects of halogen substituants on the electronic characteristics of HXC=CR2, XY=CR2 (X=H, F-I, R=H, SiMe3; Y=N, P) were studied theoretically by the MNDO, AM1 and ab initio methods using the STO-3G∗ basis set. It was found that a monotonic change in the ethylene and azaalkene electronic characteristics on proceeding from F to I was violated in the case of phosphaalkenes. It was noted that regularity in the change in the phosphaalkene characteristics is related to the halogen electron affinities. The perturbing influence of trimethylsilyl groups on the electron density distribution and on the reactivity of these compounds is discussed." @default.
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- W2020955081 date "1991-09-01" @default.
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- W2020955081 title "Halogen effects on the electronic characteristics of CC, NC and PC bonds" @default.
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