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- W2020962690 abstract "Abstract Triphenylphosphine reduces tetrakis(diethyldithiocarbamato)tellurium(IV), TeL4 [L = diethyldithiocar-bamate, (C2H5)2NCS-2] to the tellurium(II) complex Tel2, on which PPh3 has no effect. The reaction of the tellurium(IV) complex, TeL2 (X = I, Br, Cl) with PPh3 in the molar ratio of 1:1 results in the formation of TeLX, CS2 and an aminophosphonium halide, (C2H5)2NP+Ph3X−. Another mole of PPh3 reduces TeLX further to elemental tellurium. The reactions of TeL3X (X = I, ClO4, PF6) systems with excess PPh3 lead interestingly to the formation of TeL2 and elemental tellurium, with the concomitant formation of CS2, (C2H5)2NP+Ph3 X − and (C2H5)2NC(S)P+Ph3X−. The reactions were performed in dichloromethane solutions and 31P NMR spectroscopy was widely used for the identification of various phosphorus containing species." @default.
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- W2020962690 title "REACTIONS OF TRIPHENYLPHOSPHINE AND TRIBUTYLPHOSPHINE WITH TETRAETHYLTHIURAM DISULFIDE AND DIETHYLDITHIOCARBAMATE COMPLEXES OF TELLURIUM(II) AND TELLURIUM(IV)" @default.
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- W2020962690 doi "https://doi.org/10.1080/10426509608046409" @default.
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