FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2020971191> ?p ?o ?g. }

• W2020971191 endingPage "479" @default.
• W2020971191 startingPage "470" @default.
• W2020971191 abstract "Cyphos® IL-101, a tetraalkylphosphonium chloride salt (ionic liquid, IL) has been immobilized in capsules prepared by ionotropic gelation in calcium chloride solutions. The IL content was varied in the resin between 0.29 and 1.28 mmol IL g−1. These resins have been tested for Pt recovery from HCl solutions. The equilibrium was very slightly affected by the concentration of HCl and chloride ions. The sorption isotherms were modeled using the Langmuir equation: the maximum sorption capacity was influenced by the drying of the resin but remained close to 177 mg Pt g−1 for wet resin (i.e. 0.9 mmol Pt g−1, dry weight basis, or 0.7 mol Pt mol−1 Cyphos) and 142 mg Pt g−1 for dry resin (i.e. 0.73 mmol Pt g−1, or 0.57 mol Pt mol−1 Cyphos). The presence of nitrates, nickel or copper ions (added under the form of chloride salts) did not significantly decrease sorption capacity even at concentrations as high as 5 g L−1. Conversely, zinc at the concentration of 5 g L−1, significantly decreased Pt sorption, probably due to the competition effect of chloro-anionic Zn species. This is another evidence of the ion exchange mechanism involved in the binding of hexachloroplatinate species. The kinetics are weakly affected by the agitation speed (in the range 150–350 rpm) indicating that the resistance to film diffusion is not the limiting step. The kinetics are affected by the IL content, metal concentration and more specifically the drying of the resin: intraparticle diffusion sounds to be the controlling kinetic step: the intraparticle diffusion coefficient varied between 2 × 10−12 and 18 × 10−11 m2 min−1, depending on experimental conditions. Platinum can be desorbed from loaded resin using either nitric acid (5 M) or thiourea (0.1 M in 0.1 M HCl acid solution). The resin was efficiently used for three sorption/desorption cycles using nitric acid: a decrease in sorption capacity and desorption efficiency was observed beginning with the third cycle, probably due to a progressive degradation of the resin." @default.
• W2020971191 created "2016-06-24" @default.
• W2020971191 creator A5001409806 @default.
• W2020971191 creator A5010874536 @default.
• W2020971191 creator A5067297055 @default.
• W2020971191 date "2008-09-01" @default.
• W2020971191 modified "2023-10-02" @default.
• W2020971191 title "Pt recovery using Cyphos IL-101 immobilized in biopolymer capsules" @default.
• W2020971191 cites W1591593323 @default.
• W2020971191 cites W1963769566 @default.
• W2020971191 cites W1964462435 @default.
• W2020971191 cites W1965126579 @default.
• W2020971191 cites W1965437901 @default.
• W2020971191 cites W1967827455 @default.
• W2020971191 cites W1970001242 @default.
• W2020971191 cites W1973781761 @default.
• W2020971191 cites W1982376773 @default.
• W2020971191 cites W1985376741 @default.
• W2020971191 cites W1985676221 @default.
• W2020971191 cites W1986782434 @default.
• W2020971191 cites W1987027610 @default.
• W2020971191 cites W1989048570 @default.
• W2020971191 cites W1994295228 @default.
• W2020971191 cites W1998641008 @default.
• W2020971191 cites W1998986590 @default.
• W2020971191 cites W2000336543 @default.
• W2020971191 cites W2000666482 @default.
• W2020971191 cites W2001378827 @default.
• W2020971191 cites W2003222632 @default.
• W2020971191 cites W2003541136 @default.
• W2020971191 cites W2013550625 @default.
• W2020971191 cites W2014088380 @default.
• W2020971191 cites W2015851333 @default.
• W2020971191 cites W2017161504 @default.
• W2020971191 cites W2020933077 @default.
• W2020971191 cites W2022279360 @default.
• W2020971191 cites W2022734997 @default.
• W2020971191 cites W2026615598 @default.
• W2020971191 cites W2027573213 @default.
• W2020971191 cites W2028557760 @default.
• W2020971191 cites W2029013286 @default.
• W2020971191 cites W2029367489 @default.
• W2020971191 cites W2034282211 @default.
• W2020971191 cites W2038285243 @default.
• W2020971191 cites W2046728011 @default.
• W2020971191 cites W2046821360 @default.
• W2020971191 cites W2048653990 @default.
• W2020971191 cites W2052741720 @default.
• W2020971191 cites W2052822679 @default.
• W2020971191 cites W2053882891 @default.
• W2020971191 cites W2054828846 @default.
• W2020971191 cites W2056813182 @default.
• W2020971191 cites W2060894741 @default.
• W2020971191 cites W2061520111 @default.
• W2020971191 cites W2074814343 @default.
• W2020971191 cites W2082263920 @default.
• W2020971191 cites W2084607086 @default.
• W2020971191 cites W2086388845 @default.
• W2020971191 cites W2089159993 @default.
• W2020971191 cites W2090647096 @default.
• W2020971191 cites W2102399809 @default.
• W2020971191 cites W2103231233 @default.
• W2020971191 cites W2156675632 @default.
• W2020971191 cites W2157986155 @default.
• W2020971191 cites W2170667674 @default.
• W2020971191 cites W2175390068 @default.
• W2020971191 cites W2280085372 @default.
• W2020971191 cites W2782238913 @default.
• W2020971191 cites W2970581424 @default.
• W2020971191 cites W560837695 @default.
• W2020971191 cites W593501849 @default.
• W2020971191 cites W2514235759 @default.
• W2020971191 cites W897825030 @default.
• W2020971191 doi "https://doi.org/10.1016/j.seppur.2008.02.025" @default.
• W2020971191 hasPublicationYear "2008" @default.
• W2020971191 type Work @default.
• W2020971191 sameAs 2020971191 @default.
• W2020971191 citedByCount "81" @default.
• W2020971191 countsByYear W20209711912012 @default.
• W2020971191 countsByYear W20209711912013 @default.
• W2020971191 countsByYear W20209711912014 @default.
• W2020971191 countsByYear W20209711912015 @default.
• W2020971191 countsByYear W20209711912016 @default.
• W2020971191 countsByYear W20209711912017 @default.
• W2020971191 countsByYear W20209711912018 @default.
• W2020971191 countsByYear W20209711912019 @default.
• W2020971191 countsByYear W20209711912020 @default.
• W2020971191 countsByYear W20209711912021 @default.
• W2020971191 countsByYear W20209711912022 @default.
• W2020971191 countsByYear W20209711912023 @default.
• W2020971191 crossrefType "journal-article" @default.
• W2020971191 hasAuthorship W2020971191A5001409806 @default.
• W2020971191 hasAuthorship W2020971191A5010874536 @default.
• W2020971191 hasAuthorship W2020971191A5067297055 @default.
• W2020971191 hasConcept C121332964 @default.
• W2020971191 hasConcept C13965031 @default.
• W2020971191 hasConcept C148898269 @default.
• W2020971191 hasConcept C150394285 @default.

• next