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- W2020989332 abstract "Abstract Two series of iron carbonyl complexes of the types Fe(CO)4L and [CpFe(CO)2L]+ (L = water-soluble phosphines [Ph2P(CH2)nPMe3]+ n = 3, 3, 6 and 10, henceforth denoted as II-, III-, VI- and X-phophos respetively), containing neutral iron(0) and monocationic iron(II) centres respectively, have been prepared and characterized by mass spectroscopy, IR and multinuclear NMR techniques. In addition to the complexes Fe(CO)4L, disubstituted derivatives of the type trans-Fe(CO)3L2 have also been obtained as byproducts. For the complex trans-[Fe(CO)3(II-phophos)2](PF6)2, the II-phophos 31P{1H} resonances, formally an XAA′X′ spin system, exhibit virtual coupling, to our knowledge the first such example in a bis-tertiary phosphine complex in which X and X′ are 31P nuclei." @default.
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- W2020989332 date "1995-10-01" @default.
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- W2020989332 title "Neutral and cationic iron carbonyl complexes substituted with the water-soluble phosphines [Ph2P(CH2)nPMe3]+ (n = 2,3,6 and 10)" @default.
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- W2020989332 doi "https://doi.org/10.1016/0022-328x(95)05751-a" @default.
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