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• W2020989894 endingPage "1602" @default.
• W2020989894 startingPage "1595" @default.
• W2020989894 abstract "The kinetics of rubrene (5,6,11,12-tetraphenylnaphthacene) fluorescence quenching by energy transfer to the radicals of N, N, N′, N′-tetramethyl- para-phenylenediamine (TMPD+•), tetracyanoquinonedimethane (TCNQ-•) and galvinoxyl (2,6-di- tert-butyl-alpha-(3,5-di- tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)- p-tolyloxy; GAL?), have been measured in solvents of different viscosities. At room temperature the observed quenching rate constants vary between 0.12 and 7.8 × 1010 M-1 s-1, always exceeding the diffusion rate constants given by the simplest version of Smoluchowski theory combined with the rate constants for dipole–dipole energy transfer. This discrepancy is explained by accounting for the non-stationary stage in the Förster kinetics, even though the experimental fluorescence decays are apparently mono-exponential." @default.
• W2020989894 created "2016-06-24" @default.
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• W2020989894 date "2009-11-01" @default.
• W2020989894 modified "2023-09-27" @default.
• W2020989894 title "Viscosity dependence of rubrene fluorescence quenching by organic radicals via energy transfer" @default.
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• W2020989894 doi "https://doi.org/10.1039/b902433f" @default.
• W2020989894 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19862419" @default.
• W2020989894 hasPublicationYear "2009" @default.
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