FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021000701> ?p ?o ?g. }

• W2021000701 endingPage "46" @default.
• W2021000701 startingPage "33" @default.
• W2021000701 abstract "The photochemistry of a series of Os(η6-arene) complexes has been investigated in argon, methane and dinitrogen matrices with IR and UV/vis detection. The coordinatively unsaturated complex, Os(η6-C6H3Me3)(CO), may be formed by photolysis of either Os(η6-C6H3Me3)(CO)(H)2 or Os(η6-C6H3Me3)(CO)(H) in argon matrices. Irradiation of Os(η6-C6H3Me3)(CO)(H)2 in nitrogen matrices yields Os(η6-C6H3Me3)(CO)(N2). Activation of methane CH bonds occurs on photolysis of either Os(η6-C6H3Me3)(CO)(H)2 or Os(η6-C6H3Me3)(CO)2 in methane matrices. The formation of Os(η6-C6H3Me3)(CO)(CH3)(rmH) is established by comparison of a complete IR spectrum with that of an authentic sample in the matrix. These studies provide extremely strong evidence that insertion into alkane CH bonds is preceded by the information of the 16-electron intermediate Os(η6-C6H3Me3)(CO). Vinyl hydride complexes Os(η6-C6H3Me3)(L)(C2H3)(H)(rmL= CO, C2H4) and Os(η6-C6H6)(CO)(C2H3)H are formed on photolysis of the ethene complexes, Os(η6-C6H3Me3(L)(C2H4) and Os(η6-C6H6)(CO)(C2H4). The vinyl hydride products are established by comparison of the spectra from C2H4 and C2D4 complexes, and observation of OsH(D) and vinly vibrations, as well as charactersitic v(CO) modes. The photoproducts of Os(η6-C6H3Me3)(CO)(CH2=CHMe) are probably cis and trans isomers of the propenyl hydride Os(η6-C6H3Me3)(CO)(CH=CHMe)H." @default.
• W2021000701 created "2016-06-24" @default.
• W2021000701 creator A5011840391 @default.
• W2021000701 creator A5033651707 @default.
• W2021000701 creator A5049795395 @default.
• W2021000701 creator A5052000751 @default.
• W2021000701 creator A5052437108 @default.
• W2021000701 creator A5082465091 @default.
• W2021000701 creator A5086562220 @default.
• W2021000701 date "1995-11-01" @default.
• W2021000701 modified "2023-09-27" @default.
• W2021000701 title "Photochemistry of Os(η6-arene) complexes in low-temperature matrices: an infrared spectroscopic study of CH bond activation" @default.
• W2021000701 cites W1481201240 @default.
• W2021000701 cites W1965355072 @default.
• W2021000701 cites W1967159975 @default.
• W2021000701 cites W1968416158 @default.
• W2021000701 cites W1970781161 @default.
• W2021000701 cites W1975346636 @default.
• W2021000701 cites W1975891345 @default.
• W2021000701 cites W1976746957 @default.
• W2021000701 cites W1977241956 @default.
• W2021000701 cites W1981437548 @default.
• W2021000701 cites W1983107857 @default.
• W2021000701 cites W1983288108 @default.
• W2021000701 cites W1986568477 @default.
• W2021000701 cites W1986826279 @default.
• W2021000701 cites W1994949034 @default.
• W2021000701 cites W1995744702 @default.
• W2021000701 cites W2000769079 @default.
• W2021000701 cites W2000878495 @default.
• W2021000701 cites W2001646490 @default.
• W2021000701 cites W2003671829 @default.
• W2021000701 cites W2005292762 @default.
• W2021000701 cites W2008708230 @default.
• W2021000701 cites W2008728852 @default.
• W2021000701 cites W2010870113 @default.
• W2021000701 cites W2011235303 @default.
• W2021000701 cites W2011667896 @default.
• W2021000701 cites W2014091724 @default.
• W2021000701 cites W2017025427 @default.
• W2021000701 cites W2023454631 @default.
• W2021000701 cites W2026352551 @default.
• W2021000701 cites W2032843985 @default.
• W2021000701 cites W2033152097 @default.
• W2021000701 cites W2042476506 @default.
• W2021000701 cites W2044244360 @default.
• W2021000701 cites W2049186809 @default.
• W2021000701 cites W2052411917 @default.
• W2021000701 cites W2056838480 @default.
• W2021000701 cites W2059053218 @default.
• W2021000701 cites W2059207381 @default.
• W2021000701 cites W2060284852 @default.
• W2021000701 cites W2068108385 @default.
• W2021000701 cites W2069709317 @default.
• W2021000701 cites W2080141159 @default.
• W2021000701 cites W2084015557 @default.
• W2021000701 cites W2085437737 @default.
• W2021000701 cites W2088912553 @default.
• W2021000701 cites W2090553094 @default.
• W2021000701 cites W2091062610 @default.
• W2021000701 cites W2109311975 @default.
• W2021000701 cites W2123375762 @default.
• W2021000701 cites W2139425814 @default.
• W2021000701 cites W2279779346 @default.
• W2021000701 cites W2334484395 @default.
• W2021000701 cites W250153654 @default.
• W2021000701 cites W2950310038 @default.
• W2021000701 cites W2953123481 @default.
• W2021000701 cites W3004908867 @default.
• W2021000701 cites W4238570314 @default.
• W2021000701 cites W4239542072 @default.
• W2021000701 doi "https://doi.org/10.1016/0022-328x(95)05609-s" @default.
• W2021000701 hasPublicationYear "1995" @default.
• W2021000701 type Work @default.
• W2021000701 sameAs 2021000701 @default.
• W2021000701 citedByCount "16" @default.
• W2021000701 countsByYear W20210007012018 @default.
• W2021000701 crossrefType "journal-article" @default.
• W2021000701 hasAuthorship W2021000701A5011840391 @default.
• W2021000701 hasAuthorship W2021000701A5033651707 @default.
• W2021000701 hasAuthorship W2021000701A5049795395 @default.
• W2021000701 hasAuthorship W2021000701A5052000751 @default.
• W2021000701 hasAuthorship W2021000701A5052437108 @default.
• W2021000701 hasAuthorship W2021000701A5082465091 @default.
• W2021000701 hasAuthorship W2021000701A5086562220 @default.
• W2021000701 hasConcept C120665830 @default.
• W2021000701 hasConcept C121332964 @default.
• W2021000701 hasConcept C153642686 @default.
• W2021000701 hasConcept C155647269 @default.
• W2021000701 hasConcept C158355884 @default.
• W2021000701 hasConcept C178790620 @default.
• W2021000701 hasConcept C185592680 @default.
• W2021000701 hasConcept C2777207669 @default.
• W2021000701 hasConcept C2777896788 @default.
• W2021000701 hasConcept C2777961443 @default.
• W2021000701 hasConcept C2781327020 @default.
• W2021000701 hasConcept C512968161 @default.
• W2021000701 hasConcept C516920438 @default.

• next