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- W2021009062 abstract "The electro-optical and hydrodynamic properties of four synthetic polyribonucleic acids were clarified by electric birefringence methods which take the molecular-weight distribution into consideration. Parallel double-stranded helices, poly(adenylic acid)·poly(protonated adenylic acid), I, and poly(cytidylic acid)·poly(protonated cytidylic acid), II, are known to possess an electric permanent dipole moment, because the reversing-pulse electric birefringence (RPEB) signals of these duplexes exhibit dips upon pulse reversal. The RPEB signals of antiparallel double-stranded poly(adenylic acid)·poly(uridylic acid), III, and poly(guanylic acid)·poly(cytidylic acid), IV, show no dip; therefore, these polynucleotides have no permanent dipole moment. By analyzing the relaxation time of the birefringence decay signals, the axial translations of the polynucleotides per base-pair were determined to be 4.0 A for I, 2.7 A for III, and 2.4 A for IV, respectively. By analyzing the dependence of the steady-state birefrin..." @default.
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- W2021009062 date "1995-02-01" @default.
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- W2021009062 title "Electro-Optical and Hydrodynamic Properties of Synthetic Polyribonucleotides in Solutions as Studied by Electric Birefringence" @default.
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