FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021010920> ?p ?o ?g. }

• W2021010920 endingPage "6781" @default.
• W2021010920 startingPage "6774" @default.
• W2021010920 abstract "A series of hydroxo-bridged cubane-type tetrairon(II) clusters, [Fe(4)(mu-OH)(4)(mu-O(2)CAr(4)(-)t(BuPh))(2)(mu-OTf)(2)L(4)] (L = C(5)H(5)N (1), 4-(t)BuC(5)H(4)N (2), 3-FC(5)H(4)N (3)), were synthesized by using a sterically hindered carboxylate ligand, 2,6-di(4-tert-butylphenyl)benzoate (Ar(4)(-)t(BuPh)CO(2)(-)). Three different bridging units that mediate weak antiferromagnetic coupling interactions between the metal centers support the unprecedented cubane-type [Fe(4)(mu-OH)(4)](4+) cores in 1-3. The solution structures of 1 and 3 probed by FT-IR and (19)F NMR spectroscopy are consistent with the solid-state geometry determined by X-ray crystallography. Zero-field Mössbauer spectra of 1-3 at 4.2 K are characteristic of high-spin iron(II) centers in nearly identical coordination environments. Compound 1 undergoes two irreversible oxidation processes at ca -10 and +880 mV (vs Fc/Fc(+)), the former approaching quasi-reversible behavior with increased scan rates and a narrow potential sweep range. Comparisons are made with analogous known [Fe(4)X(4)](n)()(+) (X = O, S) units, and the structural integrity of tetrairon fragments upon a change in oxidation state is discussed together with some possible biological implications." @default.
• W2021010920 created "2016-06-24" @default.
• W2021010920 creator A5021530387 @default.
• W2021010920 creator A5032470300 @default.
• W2021010920 creator A5034625027 @default.
• W2021010920 creator A5037716604 @default.
• W2021010920 date "2001-11-16" @default.
• W2021010920 modified "2023-09-27" @default.
• W2021010920 title "Hydroxo-Bridged Cubane-Type Tetrairon(II) Clusters Supported by Sterically-Hindered Carboxylate Ligands" @default.
• W2021010920 cites W1973101946 @default.
• W2021010920 cites W1993480455 @default.
• W2021010920 cites W2000466466 @default.
• W2021010920 cites W2000997978 @default.
• W2021010920 cites W2013961205 @default.
• W2021010920 cites W2025599517 @default.
• W2021010920 cites W2027220042 @default.
• W2021010920 cites W2035665578 @default.
• W2021010920 cites W2038077864 @default.
• W2021010920 cites W2039616951 @default.
• W2021010920 cites W2053451848 @default.
• W2021010920 cites W2060972467 @default.
• W2021010920 cites W2065622555 @default.
• W2021010920 cites W2066920637 @default.
• W2021010920 cites W2067370875 @default.
• W2021010920 cites W2072714349 @default.
• W2021010920 cites W2081700270 @default.
• W2021010920 cites W2090079874 @default.
• W2021010920 cites W2094187872 @default.
• W2021010920 cites W209433882 @default.
• W2021010920 cites W2135620515 @default.
• W2021010920 cites W2136078186 @default.
• W2021010920 cites W2165886769 @default.
• W2021010920 cites W230345445 @default.
• W2021010920 cites W2605185437 @default.
• W2021010920 cites W4248052365 @default.
• W2021010920 doi "https://doi.org/10.1021/ic010726b" @default.
• W2021010920 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11735490" @default.
• W2021010920 hasPublicationYear "2001" @default.
• W2021010920 type Work @default.
• W2021010920 sameAs 2021010920 @default.
• W2021010920 citedByCount "23" @default.
• W2021010920 countsByYear W20210109202012 @default.
• W2021010920 countsByYear W20210109202013 @default.
• W2021010920 countsByYear W20210109202015 @default.
• W2021010920 countsByYear W20210109202016 @default.
• W2021010920 countsByYear W20210109202017 @default.
• W2021010920 countsByYear W20210109202019 @default.
• W2021010920 countsByYear W20210109202021 @default.
• W2021010920 countsByYear W20210109202022 @default.
• W2021010920 crossrefType "journal-article" @default.
• W2021010920 hasAuthorship W2021010920A5021530387 @default.
• W2021010920 hasAuthorship W2021010920A5032470300 @default.
• W2021010920 hasAuthorship W2021010920A5034625027 @default.
• W2021010920 hasAuthorship W2021010920A5037716604 @default.
• W2021010920 hasConcept C115624301 @default.
• W2021010920 hasConcept C116569031 @default.
• W2021010920 hasConcept C121332964 @default.
• W2021010920 hasConcept C155355069 @default.
• W2021010920 hasConcept C170493617 @default.
• W2021010920 hasConcept C178790620 @default.
• W2021010920 hasConcept C185592680 @default.
• W2021010920 hasConcept C201194858 @default.
• W2021010920 hasConcept C26873012 @default.
• W2021010920 hasConcept C2778074193 @default.
• W2021010920 hasConcept C2780750454 @default.
• W2021010920 hasConcept C32909587 @default.
• W2021010920 hasConcept C544153396 @default.
• W2021010920 hasConcept C55352516 @default.
• W2021010920 hasConcept C55493867 @default.
• W2021010920 hasConcept C66974803 @default.
• W2021010920 hasConcept C70854507 @default.
• W2021010920 hasConcept C71240020 @default.
• W2021010920 hasConcept C8010536 @default.
• W2021010920 hasConceptScore W2021010920C115624301 @default.
• W2021010920 hasConceptScore W2021010920C116569031 @default.
• W2021010920 hasConceptScore W2021010920C121332964 @default.
• W2021010920 hasConceptScore W2021010920C155355069 @default.
• W2021010920 hasConceptScore W2021010920C170493617 @default.
• W2021010920 hasConceptScore W2021010920C178790620 @default.
• W2021010920 hasConceptScore W2021010920C185592680 @default.
• W2021010920 hasConceptScore W2021010920C201194858 @default.
• W2021010920 hasConceptScore W2021010920C26873012 @default.
• W2021010920 hasConceptScore W2021010920C2778074193 @default.
• W2021010920 hasConceptScore W2021010920C2780750454 @default.
• W2021010920 hasConceptScore W2021010920C32909587 @default.
• W2021010920 hasConceptScore W2021010920C544153396 @default.
• W2021010920 hasConceptScore W2021010920C55352516 @default.
• W2021010920 hasConceptScore W2021010920C55493867 @default.
• W2021010920 hasConceptScore W2021010920C66974803 @default.
• W2021010920 hasConceptScore W2021010920C70854507 @default.
• W2021010920 hasConceptScore W2021010920C71240020 @default.
• W2021010920 hasConceptScore W2021010920C8010536 @default.
• W2021010920 hasIssue "26" @default.
• W2021010920 hasLocation W20210109201 @default.
• W2021010920 hasLocation W20210109202 @default.
• W2021010920 hasOpenAccess W2021010920 @default.
• W2021010920 hasPrimaryLocation W20210109201 @default.
• W2021010920 hasRelatedWork W1983726339 @default.

• next