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- W2021012839 abstract "The 1H and 19F NMR spectra of methyl mono-, di-, and trifluoroacetates have been studied in various solvents. From the solvent-dependence of the spectra, it has been established that the magnitude of the geminal H-F coupling depends on the orientation of the CHF grouping relative to the adjacent carbonyl group. The long-range H-F couplings are largest when fluorine eclipses the carbonyl group, similar to the situation observed for H-H couplings, and are probably positive. Both protons and fluorines in a-fluoroesters absorb at lower field when they are oriented gauche to the carbonyl group than when they eclipse it." @default.
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- W2021012839 title "NMR studies and rotational isomerism in fluorinated esters" @default.
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