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- W2021014352 abstract "PVDF-g-PPMA copolymers bearing pendant propargyl functionalities were prepared by thermally induced graft copolymerization of propargyl methacrylate (PMA) from the ozone-preactivated poly(vinylidene fluoride) (PVDF) backbones. Microporous membranes were fabricated from the PVDF-g-PPMA comb copolymers by phase inversion in aqueous media. The PVDF-g-PPMA membrane and pore surfaces with pendant propargyl moieties from the PPMA side chains could be further functionalized via the one-step surface-initiated thiol−yne click reaction or alkyne−azide click reaction. The electrolyte-responsive PVDF-g-P[PMA-click-MPS] membranes were prepared via thiol−yne click reaction with 3-mercapto-1-propanesulfonic acid sodium salt (MPS) on the microporous PVDF-g-PPMA membranes. The permeability of aqueous solutions through the PVDF-g-P[PMA-click-MPS] membranes exhibited a dependence on the electrolyte concentration. The PVDF-g-P[PMA-click-β-CD] membranes were synthesized via the alkyne−azide click reaction of mono(6-azido-6-desoxy)-β-cyclodextrin (azido-β-CD) on the PVDF-g-PPMA membranes. The PVDF-g-P[PMA-click-β-CD-guest-PEO] membranes, from surface inclusion complexation of diadamantyl-poly(ethylene oxide) (AD-PEO) guest polymer with the β-cyclodextrin (β-CD) host molecules, exhibited good resistance to protein adsorption and fouling under continuous-flow conditions." @default.
- W2021014352 created "2016-06-24" @default.
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- W2021014352 date "2011-05-05" @default.
- W2021014352 modified "2023-10-16" @default.
- W2021014352 title "Poly(vinylidene fluoride) Graft Copolymer Membranes with “Clickable” Surfaces and Their Functionalization" @default.
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- W2021014352 doi "https://doi.org/10.1021/ma2002728" @default.
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