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- W2021014775 abstract "Die Umsetzung von Dimethylarsin mit Metallcarbonylen liefert die funktionellen Komplexe MAs(CH3)2H (2) mit M = (CO)5Cr,(CO)5Mo,(CO)5W, C5H5(CO)2Mn,(CO)4Fe,(CO)(NO)2Fe, (CO)2(NO)Co und (CO)3Ni. Diese lassen sich durch Luft zu den Zweikernkomplexen MAs-(CH3)2As(CH3)2M (3) oxidieren, die auch aus den Metallcarbonylen und Tetramethyldiarsin zuganglich sind. An ausgewahlten Beispielen werden die Methylierung, Dehydrierung, Metallierung und Halogenierung der Komplexe 2 beschrieben.Preparation and Reactions of Dimethylarsine Metal Carbonyl ComplexesThe reaction of dimethylarsine with metal carbonyls yields the functional complexes MAs(CH3)2H (2) with M = (CO)5Cr,(CO)5Mo,(CO)5W, C5H5(CO)2Mn,(CO)4Fe,(CO)(NO)2Fe,(CO)2(NO)Co, and (CO)3Ni. They can be oxidized by air to the dinuclear complexes MAs(CH3)2As(CH3)2M (3) which are also accessible from the metal carbonyls and tetramethyldiarsine. For selected examples the methylation, dehydrogenation, metalation, and halogenation of the complexes 2 are reported." @default.
- W2021014775 created "2016-06-24" @default.
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- W2021014775 date "1977-08-01" @default.
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- W2021014775 title "Darstellung und Reaktionen von Dimethylarsin‐Metallcarbonylkomplexen" @default.
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- W2021014775 doi "https://doi.org/10.1002/cber.19771100817" @default.
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