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- W2021017991 abstract "Abstract The thermal decomposition of LnA 3 (Ln is Ce, Pr, Nd, Er; A is [CH 3 CH(CH 2 CH 3 )-(CH 2 ) 4 O] 2 PO − 2 ) 2 has been studied. It is established that heating to 443–453 K leads to recrystallization of the LnA 3 complexes accompanied by a partial annealing of the crystal defects. Their decompositions start above these temperatures and are complete at 583–608 K, producing Ln(PO 3 ) 3 . The decomposition process proceeds in a number of stages, namely the step-wise release of 6 mol of CH 3 , 6 mol of C 3 H 6 and 3 mol of C 8 H 16 O, followed by a crystallization of the metaphosphates formed. Their activation energy depends on the nature of the lanthanon and (mainly for the first decomposition stages) on the heating atmosphere. Although a strong dependence is not apparent, it is clear that these factors are of prime importance for the determination of the rate-controlling processes." @default.
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- W2021017991 date "1994-09-01" @default.
- W2021017991 modified "2023-09-27" @default.
- W2021017991 title "The thermal decomposition of solid state complexes of some rare earths (lanthanons) with bis-(2-ethylhexyl) phosphoric acid" @default.
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- W2021017991 doi "https://doi.org/10.1016/0040-6031(94)85036-4" @default.
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