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- W2021031566 abstract "Novel environmentally adapted lubricant additives were synthesized from cystine (Cys 2 ), an essential amino acid obtained from natural sources. The structural feature of cystine is a dimeric amino acid with a central disulfide bond. The carboxyl groups in Cys 2 were converted to corresponding esters by reaction with long-chain alcohols. The resultant diesters were soluble in poly-alpha-olefin (PAO) and ester-type synthetic oils. The structural features of the new additives include multifunctional groups on the same molecule, such as disulfide as a tribologically active moiety and polar functional groups as anchors to friction surfaces. The additives consist of hydrogen, carbon, nitrogen, oxygen, and sulfur; they are free of phosphorus, chlorine, and metals. The tribological properties of the additives in a solution of synthetic oil were evaluated by performing laboratory tribotests under boundary conditions. The Cys 2 -derived additives exhibited comparable antiwear properties to the conventional additive zinc dialkyldithiophosphate (ZnDTP). The additives showed good antiwear properties even at low concentrations of sulfur (160 ppm) in synthetic hydrocarbons such as PAOs. A high concentration of sulfur (640 ppm) was required to obtain an optimized antiwear performance of the synthetic esters as a base oil. The new additives reduced the friction coefficient of PAOs and synthetic esters. A saturated ester of Cys 2 reduced the friction of PAOs and synthetic esters up to oil temperatures of 150°C. The lubrication mechanism was discussed with respect to the role of functional groups in the additive molecule. The use of amino acids as versatile building blocks for the synthesis of environmentally adapted additives was also pointed out." @default.
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- W2021031566 date "2010-08-20" @default.
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- W2021031566 title "Molecular Design of Environmentally Adapted Lubricants: Antiwear Additives Derived from Natural Amino Acids" @default.
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- W2021031566 doi "https://doi.org/10.1080/10402001003728897" @default.
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