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- W2021034802 abstract "Abstract HgBa 2 CuO 4+δ (Hg-1201) and HgBa 2 Ca 2 Cu 3 O 8+δ (Hg-1223) were successfully fluorinated by XeF 2 . Fluorination of the reduced Hg-1201 phase causes the increase of T c up to 97 K which is close to that for the optimally doped oxygenated sample. Neutron powder refinements performed on HgBa 2 CuO 4 F δ samples showed that the exchange of extra oxygen for a double amount of fluorine results in shortening of the apical CuO bonds while in-plane ones (as well as T c ) do not vary. On the contrary fluorination of Hg-1223 resulted in T c enhancement up to 138 K while oxygenated sample exhibited lower T c = 134 K. From X-ray and neutron powder diffraction study we suppose that the structural factor responsible for the enhancement of T c in fluorinated Hg-1223 is shortening of the in-plane CuO distances with (CuO 2 ) layers remaining practically flat." @default.
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- W2021034802 date "2000-11-01" @default.
- W2021034802 modified "2023-09-28" @default.
- W2021034802 title "Effect of fluorination on the structure and properties of Hg-based superconducting Cu mixed oxides" @default.
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