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- W2021047369 abstract "Dipole moments of 12-crown-4, 15-crown-5 and 18-crown-6 have been measured for solutions in benzene and in cyclohexane at 15, 20, 25, and 30°, using the Guggenheim-Smith method. The dipole moments of the more common conformers of these crown ethers have also been calculated. The results indicate that these crown ethers exist in solution as mixtures of conformers. The conformational equilibria shift toward the more polar conformers as temperature increases. There is evidence that the more polar conformers of 12-crown-4 and 15-crown-5 are somewhat more favored in benzene solution than in cyclohexane, possibly as the result of a weak complexation with the former solvent." @default.
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- W2021047369 date "1988-01-01" @default.
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- W2021047369 title "Temperature and solvent effects on the experimental dipole moments of three crown ethers" @default.
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- W2021047369 doi "https://doi.org/10.1002/jhet.5570250111" @default.
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