Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021052016> ?p ?o ?g. }
- W2021052016 endingPage "8683" @default.
- W2021052016 startingPage "8673" @default.
- W2021052016 abstract "The interactions of alkyl substituted imidazolium bis(trifluoromethanolsulfonyl)imide protic ionic liquids (PILs) HCnImNTf2 (n = 0–12) were studied using vibrational spectroscopy (FT-IR/ATR and FT-Raman) and differential scanning calorimetry (DSC). The effect of alkyl substituent length (n = 0–12) and temperature on the relative magnitude of the different interactions is elucidated. For short carbon alkyl chains (n < 3), the PIL structure is affected from intramolecular interaction caused from the induction effect (+I) due to the chain substituent of the imidazolium ring, while for PILs with n > 3 the van der Waals forces between the chains and π–π interaction between neighboring imidazolium rings become important. The tendency of reducing the melting point and increasing glass transition values with the lengthening of the alkyl chain was also noticed as a result the increasing contribution of the van der Waals forces to the overall interactions. Finally, we also show that the conformational isomerism of the anion (expressed by ΔHeq) is a good indicator of the relative magnitude of the interactions. When Coulombic interactions are predominant, the trans conformer is the most probable, while when other type of interactions (HB, vdW, etc.) become important the cis conformer is favored." @default.
- W2021052016 created "2016-06-24" @default.
- W2021052016 creator A5000987701 @default.
- W2021052016 creator A5011022580 @default.
- W2021052016 creator A5069580841 @default.
- W2021052016 date "2014-07-09" @default.
- W2021052016 modified "2023-09-23" @default.
- W2021052016 title "Inter- and Intramolecular Interactions in Imidazolium Protic Ionic Liquids" @default.
- W2021052016 cites W1966793627 @default.
- W2021052016 cites W1971224763 @default.
- W2021052016 cites W1973083933 @default.
- W2021052016 cites W1977224098 @default.
- W2021052016 cites W1979262838 @default.
- W2021052016 cites W1980016399 @default.
- W2021052016 cites W1993776397 @default.
- W2021052016 cites W2011149424 @default.
- W2021052016 cites W2014483064 @default.
- W2021052016 cites W2014919752 @default.
- W2021052016 cites W2022366997 @default.
- W2021052016 cites W2023828347 @default.
- W2021052016 cites W2031758186 @default.
- W2021052016 cites W2039346309 @default.
- W2021052016 cites W2044066969 @default.
- W2021052016 cites W2045386163 @default.
- W2021052016 cites W2046550469 @default.
- W2021052016 cites W2048962488 @default.
- W2021052016 cites W2053236517 @default.
- W2021052016 cites W2057831874 @default.
- W2021052016 cites W2059289107 @default.
- W2021052016 cites W2061039250 @default.
- W2021052016 cites W2061187359 @default.
- W2021052016 cites W2061667481 @default.
- W2021052016 cites W2072201774 @default.
- W2021052016 cites W2073206670 @default.
- W2021052016 cites W2076388236 @default.
- W2021052016 cites W2081644668 @default.
- W2021052016 cites W2082708616 @default.
- W2021052016 cites W2086713708 @default.
- W2021052016 cites W2087820555 @default.
- W2021052016 cites W2091444462 @default.
- W2021052016 cites W2094051089 @default.
- W2021052016 cites W2097026728 @default.
- W2021052016 cites W2112875555 @default.
- W2021052016 cites W2115768460 @default.
- W2021052016 cites W2134994179 @default.
- W2021052016 cites W2140723396 @default.
- W2021052016 cites W2152089209 @default.
- W2021052016 cites W2162001928 @default.
- W2021052016 cites W2312270791 @default.
- W2021052016 cites W2312408191 @default.
- W2021052016 cites W2325708389 @default.
- W2021052016 cites W2335345426 @default.
- W2021052016 cites W2953794419 @default.
- W2021052016 cites W3146116847 @default.
- W2021052016 cites W4238401145 @default.
- W2021052016 doi "https://doi.org/10.1021/jp412352k" @default.
- W2021052016 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24971830" @default.
- W2021052016 hasPublicationYear "2014" @default.
- W2021052016 type Work @default.
- W2021052016 sameAs 2021052016 @default.
- W2021052016 citedByCount "30" @default.
- W2021052016 countsByYear W20210520162015 @default.
- W2021052016 countsByYear W20210520162016 @default.
- W2021052016 countsByYear W20210520162017 @default.
- W2021052016 countsByYear W20210520162018 @default.
- W2021052016 countsByYear W20210520162019 @default.
- W2021052016 countsByYear W20210520162020 @default.
- W2021052016 countsByYear W20210520162021 @default.
- W2021052016 countsByYear W20210520162022 @default.
- W2021052016 countsByYear W20210520162023 @default.
- W2021052016 crossrefType "journal-article" @default.
- W2021052016 hasAuthorship W2021052016A5000987701 @default.
- W2021052016 hasAuthorship W2021052016A5011022580 @default.
- W2021052016 hasAuthorship W2021052016A5069580841 @default.
- W2021052016 hasConcept C120665830 @default.
- W2021052016 hasConcept C121332964 @default.
- W2021052016 hasConcept C126061179 @default.
- W2021052016 hasConcept C154881586 @default.
- W2021052016 hasConcept C161790260 @default.
- W2021052016 hasConcept C178790620 @default.
- W2021052016 hasConcept C185592680 @default.
- W2021052016 hasConcept C18705241 @default.
- W2021052016 hasConcept C2778689049 @default.
- W2021052016 hasConcept C2780263894 @default.
- W2021052016 hasConcept C32909587 @default.
- W2021052016 hasConcept C39519442 @default.
- W2021052016 hasConcept C40003534 @default.
- W2021052016 hasConcept C71240020 @default.
- W2021052016 hasConcept C75079739 @default.
- W2021052016 hasConcept C8010536 @default.
- W2021052016 hasConcept C97355855 @default.
- W2021052016 hasConceptScore W2021052016C120665830 @default.
- W2021052016 hasConceptScore W2021052016C121332964 @default.
- W2021052016 hasConceptScore W2021052016C126061179 @default.
- W2021052016 hasConceptScore W2021052016C154881586 @default.
- W2021052016 hasConceptScore W2021052016C161790260 @default.
- W2021052016 hasConceptScore W2021052016C178790620 @default.
- W2021052016 hasConceptScore W2021052016C185592680 @default.