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• W2021052983 abstract "A new synthetic sequence that adds the elements of ketene across the termini of a 1,5-diene is described. Dichlorocyclobutanone adducts from reaction of dichloroketene with 1,5-dienes undergo intramolecular free radical annulation. Lewis acid-promoted ring-opening of the cyclized cyclobutanones then yields novel ring expansion products. Reaction of (R)-carvone provides an unusual example leading to the formation of a tricyclic dione. The carbonyl group of carvone enhances the radical cyclization and influences the ring-opening pathway." @default.
• W2021052983 created "2016-06-24" @default.
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• W2021052983 date "1995-03-01" @default.
• W2021052983 modified "2023-09-24" @default.
• W2021052983 title "Free radical annulation of dichlorocyclobutanones with sequential ring expansion" @default.
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• W2021052983 doi "https://doi.org/10.1016/0040-4020(95)00093-n" @default.
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