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- W2021054782 abstract "To explore the relationship between solvatochromic parameters and chiral selectivity, we measured the effect of organic solvents as buffer additives on the chiral selectivities of dansyl-phenylalanine, dansyl-leucine, and propranolol by β-cyclodextrin in capillary electrophoresis. Negative relationships between the additive's log L16 and chiral selectivities were observed for the systems added C1–C6 alcohols, C1–C5 amines, and C1–C5 acids. The chiral selectivities also decreased significantly with the additive's increasing hydrogen bond basicity. The decreased selectivities of additives on dansyl-phenylalanine is much greater than on dansyl-leucine. The chiral selectivities of propranolol remained unchanged with all the additives in the buffer. Although most additives studied decreased chiral selectivities, the data presented in this work provided some initial information on chiral selectivities relating to solvatochromic parameters." @default.
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- W2021054782 date "1998-12-01" @default.
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- W2021054782 title "Effect of additives on chiral selectivities by β-cyclodextrin in capillary electrophoresis based on the phenomenon of solvatochromism" @default.
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- W2021054782 doi "https://doi.org/10.1016/s0021-9673(98)00761-4" @default.
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