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- W2021061738 abstract "A new ligand formation was observed in the title complex, [Cu(C4H4N3O2){N(CN)2}(C10H8N2)], as a result of the nucleophilic addition reaction between methanol and dicyanonitrosomethanide in the inner coordination sphere of a CuII atom. This new ligand, 3-amino-3-methoxy-2-nitrosoacrylonitrilate (add) [NHC(OMe)C(CN)NO]−, is coordinated as a chelate, forming a five-membered metallocycle with CuII. The distorted tetragonal-pyramidal coordination is completed by one chelate-coordinated molecule of 2,2′-bipyridine (bipy) and one end-coordinated dicyanamide anion, [N(CN)2]−. The four N atoms of the two metallocycles form the base and a fifth N-atom, from the dicyanamide anion, forms the apex of the pyramid, creating a {CuN5} chromophore. The structure of [Cu(add)(bipy){N(CN)2}] XX consists of discrete molecules." @default.
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- W2021061738 date "1996-10-15" @default.
- W2021061738 modified "2023-10-13" @default.
- W2021061738 title "Addition of Methanol to Copper(II)-Coordinated Dicyanonitrosomethanide: (3-Amino-3-methoxy-2-nitrosoacrylonitrilato-N2,N3)(bipyridine-N,N')(dicyanamido-N)copper(II)" @default.
- W2021061738 doi "https://doi.org/10.1107/s0108270196009766" @default.
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