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- W2021069742 abstract "Mild, efficient and racemization-free synthesis of N-protected α, β-unsaturated γ-amino esters with unprecedented high E- stereoselectivity is described. This method is found to be compatible with Boc-, Fmoc- and other side chain protecting groups. The crystal conformations of the vinylogous γ-amino esters in monomers and in homo- and mixed dipeptides are studied. Further, the vinylogous homo-dipeptide showed a β-sheet conformation, while mixed α- and α,β-unsaturated γ-hybrid dipeptide adapted an irregular structure in single crystals." @default.
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- W2021069742 date "2011-01-01" @default.
- W2021069742 modified "2023-10-02" @default.
- W2021069742 title "Synthesis of α, β-unsaturated γ-amino esters with unprecedented high (E)-stereoselectivity and their conformational analysis in peptides" @default.
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- W2021069742 doi "https://doi.org/10.1039/c1ob05732d" @default.
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