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• W2021070001 endingPage "142" @default.
• W2021070001 startingPage "134" @default.
• W2021070001 abstract "The chemistry of copper(I) halides (CuX) with furan-2-carbaldehyde-N1-substituted thiosemicarbazones {(C4H3O)HC2N3N2H–C1(S)N1HR, Hftsc-N1HR} in presence of triphenyl phopshine is described. For methyl and ethyl substituents (R) at N1 atom, and with X = I, Br, Cl, the halogen-bridged dimers, namely, [Cu2(μ-X)2(η1-S-Hftsc-N1HR)2(PPh3)2] (R, X: Me, I, 1, Br 2, Cl 3; Et, I 4, Br 5, Cl 6) have been obtained. However, the presence of phenyl substituent at N1 has favored a three coordinate complex, [CuI(η1-S-Hftsc-N1HPh)2] 7, and with copper(I) bromide/and chloride, it has formed sulfur-bridged dimers, [Cu2X2(η1-Hftsc-N1HPh)2(μ-S-Hftsc N1HPh)2] (X = Br 8, Cl 9). In the latter three complexes (7–9), the Ph3P ligand did not take part in coordination. All these complexes have been characterized with the help of elemental analysis, IR, 1H NMR spectroscopy and X-ray crystallography (1–3, 5, 7 and 9). The bonding and nuclearity of complexes has been found to vary with the substituents at N1 atom. The intermolecular interactions have formed one dimensional (1, 9) and two dimensional (2, 3 and 5) networks." @default.
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• W2021070001 date "2012-10-01" @default.
• W2021070001 modified "2023-09-25" @default.
• W2021070001 title "The influence of substituents (R) at N1 atom of furan-2-carbaldehyde thiosemicarbazones {(C4H3O)HC2N3–N(H)–C1(S)N1HR} on bonding, nuclearity, H-bonded networks of copper(I) complexes" @default.
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• W2021070001 doi "https://doi.org/10.1016/j.poly.2012.08.014" @default.
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