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- W2021076239 abstract "Abstract A series of malonamides possessing two quinoline moieties were synthesized and characterized as fluoroionophores for the Zn 2+ ion. We focused on the relationship between the substituents introduced to the C2-position of the malonamides and their Zn 2+ ion-selectivity, exploiting the structural effect of the substituents in the design of the fluoroionophores with high selectivity. The substituents introduced to the malonamides were the methyl, benzyl and naphthalenylmethyl groups. In dimethyl sulfoxide solvent, all substituted bisquinolinyl malonamides showed excellent fluorescence sensing for the Zn 2+ ion, while unsubstituted bisquinolinyl malonamide 1 displayed ratiometric sensing for the Co 2+ ion. N , N ′-Bis(8-quinolyl)-2-methyl-2-naphthalenylmethyl malonamide 4 exhibited the highest Zn 2+ ion-selectivity against the Cd 2+ ion. Although the substituents introduced into the C2-position are spatially distant from the quinoline recognition moiety, this study indicated that they greatly influenced the ion selectivities of the bisquinolinyl malonamides. Furthermore, it was demonstrated that visible fluorescence analyses could be performed on malonamide 4 ." @default.
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- W2021076239 date "2014-12-01" @default.
- W2021076239 modified "2023-09-24" @default.
- W2021076239 title "Design of bisquinolinyl malonamides as Zn2+ ion-selective fluoroionophores based on the substituent effect" @default.
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- W2021076239 doi "https://doi.org/10.1016/j.tet.2014.11.016" @default.
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