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- W2021096633 abstract "8-Bromoquinoline reacts with zincated cyclopentadienyl derivatives of Fe, Mn, and Re in the presence of bis(triphenylphosphine)palladium(0) to yield the corresponding 8-quinolylcyclopentadienyl metal complexes. Tricarbonyl[η5-(8-quinolyl)cyclopentadienyl]manganese(I) (5) and tricarbonyl[η5-(8-quinolyl)cyclopentadienyl]rhenium(I) (6) eliminate CO upon irradiation to form dicarbonyl[η5-(8-quinolyl)cyclopentadienyl]manganese(I) (7) and dicarbonyl[η5-(8-quinolyl)cyclopentadienyl]rhenium(I) (8), respectively. The intensely coloured complexes 7 and 8 show solvatochromism, which has been investigated in more detail. Coordination of the quinolyl moiety in 7 and 8 could be proved by spectroscopy and by crystal structure determination." @default.
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- W2021096633 date "2001-03-01" @default.
- W2021096633 modified "2023-10-17" @default.
- W2021096633 title "Synthesis and coordination behaviour of the new (8-quinolyl)cyclopentadienyl ligand" @default.
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- W2021096633 doi "https://doi.org/10.1016/s0022-328x(00)00866-4" @default.
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