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• W2021097407 abstract "Abstract An EPR study on the Brownian motion of bis( L ‐ N , N ‐dimethylvalinato)copper( II ), Cu( L ‐Me 2 Val) 2 and bis( L ‐ N , N ‐dimethylleucinato)copper( II ), Cu( L ‐Me 2 Leu) 2 , dissolved in different solvents (CD 3 OD, CH 3 CH 2 OH, CDCl 3 ) as a function of temperature is presented. The theoretical fits of the EPR spectra revealed different EPR behaviour for the two copper( II ) complexes in hydrogen bond making solvents. In order to examine whether the different behaviour could be explained on conformational (steric) grounds, a conformational analysis of the copper( II ) complexes with L ‐ N , N ‐dimethylated amino acids was performed with a molecular mechanics force field. The ability of the most stable conformations to bind a water molecule in the copper( II ) first coordination sphere was also examined using the force field. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
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• W2021097407 date "2004-09-21" @default.
• W2021097407 modified "2023-10-11" @default.
• W2021097407 title "Conformational Analysis of Bis( <scp>L</scp> ‐ <i>N</i> , <i>N</i> ‐dimethylvalinato)copper( <scp>II</scp> ) and Bis( <scp>L</scp> ‐ <i>N</i> , <i>N</i> ‐dimethylleucinato)copper( <scp>II</scp> ) in Different Solvents by EPR Spectroscopy and a Molecular Mechanics Study" @default.
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• W2021097407 doi "https://doi.org/10.1002/ejic.200300781" @default.
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