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• W2021100790 abstract "Highly dispersed and nearly uniformly sized Hf1-xEuxO2-x/2 (x = 0.05, 0.1, and 0.15) solid solution nanoparticles with particle sizes between 2.2 and 5.2 nm were produced via the hydrothermal treatment of a metal−oleate complex precursor at 200 °C for 6 h. The obtained nanocrystals were characterized by IR, EDX, XRD, Raman scattering, TEM, and PL spectroscopy. It was demonstrated that the proposed synthetic technique led to the formation of a Hf1-xEuxO2-x/2 solid solution with a thermodynamically metastable phase (tetragonal HfO2 phase). Pure HfO2 nanocrystals were rod-like in shape with a monoclinic phase, while the doping of HfO2 by Eu3+ resulted in the nearly spherically shaped nanocrystals. The PL spectroscopy showed significant quenching of Eu3+ 5Do → 7Fn radiative transitions for the as-prepared samples, whereas the annealed sample at 400 °C for 5 h showed clear red luminescence." @default.
• W2021100790 created "2016-06-24" @default.
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• W2021100790 date "2008-03-12" @default.
• W2021100790 modified "2023-09-24" @default.
• W2021100790 title "Rational Hydrothermal Route to Monodisperse Hf_1-<i>_x</i>Eu<i>_x</i>O_2-<i>_x</i>_/2 Solid Solution Nanocrystals" @default.
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• W2021100790 doi "https://doi.org/10.1021/jp710673y" @default.
• W2021100790 hasPublicationYear "2008" @default.
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